Understanding the life of lithium ion batteries in electric vehicles

April 10, 2013 - via American Chemical Society

(Nanowerk News) Scientists today answered a question that worries millions of owners and potential owners of electric and hybrid vehicles using lithium-ion batteries: How long before the battery pack dies, leaving a sticker-shock bill for a fresh pack or a car ready for the junk heap? Their answer, presented at the 245th National Meeting & Exposition of the American Chemical Society (ACS), being held here this week, may surprise skeptics.

“The battery pack could be used during a quite reasonable period of time ranging from 5 to 20 years depending on many factors,” said Mikael G. Cugnet, Ph.D., who spoke on the topic. “That’s good news when you consider that some estimates put the average life expectancy of a new car at about eight years.

Cugnet explained that the lifespan depends mainly on the battery’s temperature, state of charge and charge protocol. Battery performance begins to suffer as soon as the temperature climbs above 86 degrees Fahrenheit. “The higher the temperature, the lower the battery service life,” he said. “A temperature above 86 degrees F affects the battery pack performance instantly and even permanently if it lasts many months like in Middle East countries.” Cugnet also recommended that electric vehicle (EV) owners pay attention to how much their battery is charged, another factor in a battery’s longevity. He reported that a fully-charged battery is more vulnerable to losing power at temperatures above 86 degrees F.

To test the limits of lithium-ion EV batteries, Cugnet’s team reconstructed the experience of a typical EV battery in the laboratory. Using data gleaned from a real five-mile trip in an EV, they put EV battery packs and cells through simulated lifetimes of driving with cycles of draining and recharging. The researchers considered a battery to be beyond its useful lifespan when it had lost 20 percent of its full power.

The question of longevity matters to EV owners and manufacturers alike. The cost of the lithium-ion batteries that power these vehicles remains high, and an EV can cost twice as much as a gas or diesel equivalent. Customers want to make sure they get their money’s worth, and manufacturers are eager to demonstrate that EVs are economical.

One obvious saving is the cost of fuel over a car’s lifetime, but EV makers are also pushing so-called “second life” uses for batteries that could make them valuable even after they’ve lost too much power to be useful in cars. These applications could include backup power for computers and medical equipment, or electrical grid storage, which would go hand-in-hand with renewable power like wind or solar to keep electricity flowing even when environmental conditions aren’t right. Another option is recycling a battery’s components to make new batteries.

The American Chemical Society is a nonprofit organization chartered by the U.S. Congress. With more than 163,000 members, ACS is the world’s largest scientific society and a global leader in providing access to chemistry-related research through its multiple databases, peer-reviewed journals and scientific conferences. Its main offices are in Washington, D.C., and Columbus, Ohio.

The market of Li-ion batteries is growing fast mainly due to the electric vehicle rebirth. However, the anticipated demand in electric vehicles is much lower than it was originally announced, since they can cost twice as much as similar gas-powered vehicles. Battery costs will unfortunately stay high until they can be made at high volumes.

Among the various ways identified to decrease their price is the possibility of a battery second life in otherapplications, less demanding in power capability, such as utility storage. This means that batteries should not only be able to operate during the complete vehicle life, but also long after. Therefore, there is a need to investigate the way they degrade during rest (calendar life) and operation (cycle life) depending on the vehicle characteristics. This will help to improve the battery design, the battery management system, and consequently the electric vehicle competitiveness.

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